Refereed Publications
(*Indicates research students directly supervised by Andrea M. Goforth)
1. *Chiu, S.-K., *Manhat, B.M., *DeBenedetti, W.J.I., *Brown, A.L., Fichter, K., Vu, T., Eastman, M.; Jiao, J., Goforth, A.M. Aqueous red-emitting silicon nanoparticles for cellular imaging: Consequences of protecting against surface passivation by hydroxide and water for stable, red emission. J. Mater. Chem., 2013, 28, 216; DOI: 10.1557/jmr.2002.337.
2. Qian, W.; Hao, R; Zhou, J.; Eastman, M.; *Manhat, B.A.; Sun, Q.; Goforth, A.M.; Jiao, J. Exfoliated graphene-supported Pt and Pt-based alloys as electrocatalysts for direct methanol fuel cells. Carbon, 2013, 52, 595; DOI: 10.1016/j.carbon.2012.10.031.
3. *Brown, A.L.; Goforth, A.M. pH-dependent synthesis and stability of elemental, aqueous bismuth glyconanoparticle colloids: Potentially biocompatible X-ray contrast agents. Chem. Mater., 2012, 24, 1559; DOI: 10.1021/cm300083.
4. Qian, W.; Chen, Z.; Eastman, M.; Cottingham, S.; *Manhat, B.A.; Goforth, A.M.; Jiao, J. Complimentary microscopy techniques applied for optimizing the structure and performance of graphene-based hybrids. Ultramicroscopy, 2012, 119, 97; DOI: 10.1016/j.ultramic.2011.11.010.
5. Qian, W.; Chen, Z.; Cottingham, S.; *Merrill, W.A.; Swartz, N.A.; Goforth, A.M.; Lasseter Clare, T.; Jiao, J. Surfactant-free hybridization of transition metal oxide nanoparticle with conductive graphene for high performance supercapacitor. Green Chem., 2012, 14, 371; DOI: 10.1039/c1gc16134b.
6. *Manhat, B.A.; ^Brown, A.L.; Black, L.; Ross, J.B.A.; Fichter, K.; Vu, T.; Richman, E.; Goforth, A.M. One-step, melt synthesis of water soluble, photoluminescent, surface-oxidized silicon nanoparticles for cellular imaging applications. Chem. Mater., 2011, 23, 2407; DOI: 10.1021/cm200270d.
7. Goforth, A.M.; *Tershansy, M.A.; Smith, M.D.; Peterson, Jr., L.; Kelly, J.G.; *DeBenedetti, W.J.I; zur Loye, H.-C. Structural diversity and thermochromic properties of iodobismuthate materials containing d-metal coordination cations: Observation of a high symmetry [Bi3I11]2- anion and of isolated I- anions. J. Am. Chem. Soc., 2011, 133, 603; DOI: 10.1021/ja108278j.
8. Ma, X.; Xu, F.; Atkins, T.; Goforth, A.M.; Neiner, D.; Navrotsky, A.; Kauzlarich, S.M. A Versatile Low Temperature Synthetic Route to Zintl Phase Precursors: Na4Si4, Na4Ge4, and K4Ge4 as Examples. Dalton Trans., 2009, 10250; DOI: 10.1039/b913320h.
9. Goforth, A.M.; Hope, H.; Condron, C.L.; Kauzlarich, S.M.; Jensen, N.; Klavins, P.; Fisk, Z. Magnetism and Negative Magnetoresistance of Two Magnetically Ordering, Rare-Earth-Containing Zintl Phases with a New Structure Type: EuGa2Pn2 (Pn = P, As). Chem. Mater., 2009, 21, 4480. DOI: 10.1021/cm901219u.
10. Goforth, A.M.; Klavins, P.; Fettinger, J.C.; Kauzlarich, S.M. Magnetic Properties and Negative Colossal Magnetoresistance of the Rare Earth Zintl Phase EuIn2As2. Inorg. Chem., 2008, 47, 11048. DOI: 10.1021/ic801290u.
11. *Tershansy, M.A.; Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. [Co(phen)3]2[Cu11I15]: A mixed- metal iodocuprate containing the novel [Cu10I15]5- and [Cu12I15]3- clusters. Cryst. Eng. Commun., 2008, 10, 833. DOI: 10.1039/b716031c.
12. *Tershansy, M.A.; Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. The synthesis and crystal structure of [BiI2(tpy)2][Bi2I7(tpy)]: A new metal halide material. J. Chem. Cryst., 2008, 38, 453. DOI: 10.1007/s10870-008-9342-x.
13. *Tershansy, M.A.; Goforth, A.M.; Peterson, Jr., L.; Burns, M.C.; Smith, M.D.; zur Loye, H.-C. Syntheses and crystal structures of new chain-containing iodometallate compounds: (H1,10- phen)(H2O)1.41[AgI2]; (H1,10-phen)(H2O)1.42[CuI2]; [Co(tpy)2][Bi2I8]; [Fe(tpy)2][Bi2I8]; [Co(1,10- phen)3][Pb3I8]•H2O, and [Fe(1,10-phen)3][Pb3I8]•0.5(H2O). Solid State Sci., 2007, 9, 895. Cover Article. DOI: 10.1016/j.solidstatesciences.2007.06.018.
14. *Tershansy, M.A.; Goforth, A.M.; Gardinier, J.R.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. Solvothermal syntheses, high and low-temperature crystal structures, and thermochromic behavior of [1,2-diethyl-3,4,5-trimethyl-pyrazolium]4[Bi4I16] and [1,10-phenanthrolinium][BiI4]•(H2O). Solid State Sci., 2007, 9, 410. Cover article. DOI: 10.1016/j.solidstatesciences.2007.03.010.
15. Perkins, W.J.; Maxwell, T.; Williams, K.B.; Goforth, A.M.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. catena-Poly[[bis(α-thenoyltrifluoroacetonato-κ2O,O’)copper(II)]-μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene)-κ2N:N’]. Acta Cryst. 2007, E63, m423. DOI: 10.1107/S1600536807000311.
16. Paulin, S.; Kelly, P.; Williams, K.B.; Goforth, A.M.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. catena-Poly[[diaquadinitratozinc(II)]bis(μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene)]. Acta Cryst. 2007, E63, m420. DOI: 10.1107/S1600536807000281.
17. Chen, C.-L.; Ellsworth, J.M.; Goforth, A.M.; Smith, M.D.; Su, C.-Y.; zur Loye, H.-C. A new 2-carboxylate-substituted 4,4’-bipyridine ligand: Coordination chemistry of 4,4’-bipyridine-2-carboxylic acid and its synthetic intermediate 2-methyl-4,4’-bipyridine. Dalton Trans. 2006, 44, 5278. DOI: 10.1039/b606280f.
18. *Tershansy, M.A.; Goforth, A.M.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. Bis(1,10- phenanthroline)dibismuthhexaiodide. Acta Cryst. 2006, E62, m2987. DOI: 10.1107/S1600536806041997.
19. Goforth, A.M.; *Tershansy, M.A.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. Tris(2,2’- bipyridine)ruthenium(II) doicosaiodobismuthate and 2,2’-bipyridinium doicosaiodobismuthate. Acta Cryst. 2006, C62, m381. DOI: 10.1107/S0108270106025972.
20. Ellsworth, J.M.; Su, C.-Y.; Khaliq, Z; *Hipp, R.E.; Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. Synthesis, characterization, and crystal structures of novel coordination compounds assembled from the reaction of the asymetric, chelating ligand 2-(4-pyridyl)thiazole-4-carboxylic acid with Zn2+ and Ag+ ions. J. Mol. Struct. 2006, 796, 86. DOI: 10.1016/j.molstruc.2006.03.034.
21. Chen, C.-L.; Goforth, A.M.; Smith, M.D.; Gemmill, W.R.; Su, C.-Y.; zur Loye, H.-C. Synthesis and single crystal structure of a new dinuclear copper(II) complex of 1,5-bis(8-oxaquinoline)-3- methylpentane. J. Cluster Sci. 2005, 16, 477. DOI: 10.1007/s10876-005-0004-2.
22. Perkins, W.J.; Maxwell, T.; Goforth, A.M.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. catena-poly[Cu(1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene)2(tta)2], (tta = α-thenoyltrifluoroacetonato). Acta Cryst. 2005, E61, m2047. DOI: 10.1107/S1600536805028631.
23. Chen, C.-L.; Goforth, A.M.; Smith, M.D.; Su, C.-Y.; zur Loye, H.-C. Non-interpenetrated square grid coordination polymers synthesized using an extremely long N,N’-type ligand. Inorg. Chem. 2005, 44, 8762. DOI: 10.1021/ic051068o.
24. Goforth, A.M.; Peterson, Jr., L.; Smith, M.D.; zur Loye, H.-C. Syntheses and crystal structures of several novel alkylammonium iodobismuthate materials containing the 1,3-bis-(4- piperidinium)propane cation. J. Solid State Chem. 2005, 178, 3529. DOI: 10.1016/j.jssc.2005.09.010.
25. Chen, C.-L.; Goforth, A.M.; Smith, M.D.; Su, C.-Y.; zur Loye, H.-C. Co2(PPCA)2(H2O)(V4O12): A new framework material exhibiting reversible shrinkage and expansion via a single crystal to single crystal transformation involving a change in the cobalt coordination environment (PPCA = 4,4’- bipyridyl-2-carboxylate). Angew. Chem., Int. Ed. 2005, 44, 6673. DOI: 10.1002/anie.200502309.
26. Goforth, A.M.; Gerth, K.; Smith, M.D.; Shotwell, S.; Bunz, U.H.F.; zur Loye, H.-C. Channel- containing structures generated form linear coordination polymer chains containing N,N’-bidentate ligands and Cu-Cu dimetal units. Solid State Sci. 2005, 7, 1083.
27. Fiscus, J.E., Shotwell, S.; Layland, R.C.; *Hipp, R.E., Goforth, A.M.; Chapman, C.T.; Smith, M.D.; Bunz, U.H.F.; zur Loye, H.-C. Coordination dimers constructed from metal(II) halides and the new ligand 1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene. J. Chem. Crystallogr. 2005, 35, 903. DOI: 10.1007/s10870-005-5136-6.
28. Goforth, A.M.; Su, C.-Y.; *Hipp, R.E.; Macquart, R.B.; Smith, M.D.; zur Loye, H.-C. Connecting small ligands to generate large tubular metal-organic architectures. J. Solid. State Chem. 2005, 178, 2511. DOI: 10.1016/j.jssc.2005.05.038.
29. *Tershansy, M.A.; Goforth, A.M.; Peterson, Jr., L.; Smith, M.D.; zur Loye, H.-C. Tris(1,10- phenanthroline)cobalt(II) triiodide. Acta Cryst. 2005, E61, m1680. DOI: 10.1107/S1600536805023883.
30. Goforth, A.M.; Gardinier, J.R.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. [Ru(2,2’- bipy)3]2[Bi4I16]: A bimetallic inorganic-organic complex consisting of a d-metal coordination cation and a polynuclear iodobismuthate anion. Inorg. Chem. Commun. 2005, 8, 684. DOI: 10.1016/j.inoche.2005.03.028.
31. Goforth, A.M.; *Hipp, R.E; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. Tris(ethylenediamine)cobalt(III) nonaiodobismuthate. Acta Cryst. 2005, E61, m1531.
32. Fiscus, J.E.; Pschirer, N.G.; *Hipp, R.E.; Goforth, A.M.; Chapman, C.T.; Shotwell, S.; Layland, R.C.; Smith, M.D.; zur Loye, H.-C. Synthesis and structural characterization of five new coordination polymer chain structures using a new, Z-shaped ligand, 2,2’-bis-(4- pyridylethynyl)tolane. J. Chem. Crystallogr. 2005, 35, 125. DOI: 10.1007/s10870-005-2801-8.
33. Kallil, S.; Peterson, Jr., L.; Goforth, A.M.; Hansen, T.J.; Smith, M.D.; zur Loye, H.-C. Synthesis, crystal structure, and thermal properties of {Cd2(L1)3(sac)4]•2CH2Cl2}∞: A coordination polymer with non-interpenetrating ladders containing cadmium in a rare, trigonal bipyramidal coordination environment (L1 = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene, sac = saccharinate). J. Chem. Crystallogr. 2005, 35, 405. DOI: 10.1007/s10870-005-1694-x.
34. Grant, G.J.; Chen, W.; Goforth, A.M.; Baucom, C.L; Patel, K.; Repovic, P.; VanDerveer, D.G.; Pennington, W.T. Anion and solvent effects upon the structures of platinum(II) complexes with thiacrown ligands: The crystal structures of [Pt(9S3)2](PF6)2•2CH3NO2, [Pt(9S3)2](BF4)2•2CH3NO2, [Pt(9S3)2](OTf)2•2CH3NO2 and [Pt(18S6)](BF4)2. Eur. J. Inorg. Chem. 2005, 479. DOI: 10.1002/ejic.200400461.
35. Goforth, A.M.; Smith, M.D.; Peterson, Jr., L.; zur Loye, H.-C. Preparation and characterization of novel inorganic-organic hybrid materials containing rare, mixed halide anions of bismuth(III). Inorg. Chem. 2004, 43, 7042. DOI: 10.1021/ic049212d.
36. Su, C.-Y.; Smith, M.D.; Goforth, A.M.; zur Loye, H.-C. A three-dimensional, non-interpenetrating metal-organic framework with the moganite topology: A simple (42.62.82)(4.64.8)2 net containing two kinds of topologically nonequivalent points. Inorg. Chem. 2004, 43, 6881. DOI: 10.1021/ic048812+.
37. Su, C.-Y.; Goforth, A.M.; Smith, M.D.; Pellechia, P.J.; zur Loye, H.-C. Exceptionally stable hollow tubular metal-organic architectures: Synthesis, characterization, and solid state transformation study. J. Am. Chem. Soc. 2004, 126, 3576. DOI: 10.1021/ja039022m.
38. Su, C.-Y.; Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. Assembly of large simple 1D and rare polycatenated 3D molecular ladders from T-shaped building blocks containing a new, long N,N’- bidentate ligand. Chem. Commun. 2004, 2158. DOI: 10.1039/b406126h.
39. Davis, H.; Peterson, Jr., L,; Goforth, A.M.; Smith, M.D.; Zhang, P.; zur Loye, H.-C. Crystal structure and characterization of [Co(saccharinate)2(L1)(H2O)2]n solvate: A new microporous coordination polymer generated from 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (L1) and [Co(saccharinate)2•4H2O]•2H2O. J. Chem. Crystallogr. 2004, 34, 299. DOI: 10.1023/B:JOCC.0000026274.31401.7f.
40. Grant, G.J.; Goforth, A.M.; Smith, VanDerveer, D.G.; Pennington, W.T. Homoleptic Platinum(II) and Palladium(II) Complexes of 1,5,9-trithiacyclododecane: The crystal structures of [Pt(12S3)2][PF6]2•2CH3NO2 and [Pd(12S3)2](BF4)2•0.5H2O. Inorg. Chim. Acta 2004, 357, 2107. DOI: 10.1016/j.ica.2003.10.033.
41. Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. Synthesis and crystal structure of the two- dimensional coordination polymer catena-(bis(μ3-iodo)-(μ2-pyrazine)-di-copper(I)). J. Chem. Crystallogr. 2003, 33, 303. DOI: 10.1023/A:1023841413142.
42. Su, C.-Y.; Goforth, A.M.; Smith, M.D.; zur Loye, H.-C. Formation of dinuclear, macrocyclic, and chain structures from HgI2 and a semirigid benzimidazole-based bridging ligand: An example of ring-opening supramolecular isomerism. Inorg. Chem. 2003, 42, 4685. DOI: 10.1021/ic034388l.
43. Chapman, C.T.; Goforth, A.M.; Pschirer, N.G.; Smith, M.D.; Bunz, U.H.F.; zur Loye, H.-C. Synthesis and crystal structure of catena-poly[Rh2(OAc)4(C27H15N3)]•2CH2Cl2, a novel Rh(II) organic/inorganic coordination polymer. J. Chem. Crystallogr. 2003, 33, 885. DOI: 10.1023/A:1027414030899.
44. Li, Y.-H.; Su, C.-Y.; Goforth, A.M.; Shimizu, K.D.; Gray, K.D.; Smith, M.D.; zur Loye, H.-C. The first ‘two-over/two-under’ (2O/2U) 2D weave structure assembled from Hg-containing 1D coordination polymer chains. Chem. Commun. 2003, 1630. DOI: 10.1039/b303708h.
Non-refereed Publications
(*Indicates research students directly supervised by Andrea M. Goforth)
1. *Brown, A.L.; Goforth, A.M. Bismuth particle X-ray contrast agents. International patent application pending, PCT/US2012/041147, filed June 2012. Pub. No. WO/2012/170569, Publication Date 12/13/2012, International Filing Date 06/06/2012.